Complex Chemistry by John Emsley; et al PDF

By John Emsley; et al

ISBN-10: 0387134115

ISBN-13: 9780387134116

ISBN-10: 3540134115

ISBN-13: 9783540134114

Content material: constitution and bonding in metal-pentadienyl and similar compounds / R.D. Ernst -- a brand new examine the stereochemistry and digital homes of complexes of the copper(II) ion / B.J. Hathaway -- Calculations of the Jahn-Teller coupling constants for dx platforms in octahedral symmetry through the angular overlap version / K.D. Warren -- The composition, constitution, and hydrogen bonding of the B-diketones / J. Emsley

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Chem. Soc. 92, 7622 (1970) 109. Hegarty, A. , Coy, J. , Scott, F. : J. Chem. , Perkin II, 104 (1975) 110. Lehr, R. E. : J. Am. Chem. Soc. 98, 4867 (1976) 111. : ibid. 98, 6037 (1976) 112. Olah, G. A. : ibid. 100, 6299 (1978) 113. : Angew. Chem. Intl. Ed. ) 21, 145 (1982) 114. O'Brien, D. , Hart, A. , Russell, C. : J. Am. Chem. Soc. 97, 4410 (1975) 115. Olah, G. , Yu, S. : J. Org. Chem. 41, 2383 (I976) 116. Birch, A. , Westerman, P. , Pearson, A. : Aust. J. Chem. 29, 1671 (1976) 117. Wilson, D. , Ernst, R.

027 for the sextet state. This value is substantially less than that for the previous nickel compound, and indicates that the manganese-manganese interactions are dominated by electrostatic forces as a result of substantial but opposite charges existing on adjacent manganese centers. The calculations would therefore almost seem to describe the central manganese atom as a nearly "naked" manganese atom. However, if it is possible to bring about Lewis base coordination to this atom, it seems quite likely that net positive charge could be induced onto it, more akin to the original formulation as Mn 2+ [Mn(3-C6H9)212248).

Claim. Acta. 63, 555 (1980) 76. Yasuda, H. : Organometallics 2, 21 (1983) 77. : Tet. Lett. 27, 2443 (1973) 78. Yasuda, H. : Bull. Chem. Soc. Jpn. 52, 2036 (1979) 79. , Ford, W. : J. Org. Chem. 39, 232 (1974) 80. Bates, R. B. : J. Am. Chem. Soc. 91, 4608 (1969) 81. , VanDrunen, J. A. : Recl. Trav. Chim. Pays-Bas 88, 1084 (1969) 82. Bates, R. , C01e, C. : J. Am. Chem. Soc. 94, 2130 (1972) 83. Bates, R. , Mayall, B. : ibid. 94, 4765 (1972) 84. Bates, R. B. : ibid. 96, 5640 (1974) 85. Bahl, J. J. : ibid.

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Complex Chemistry by John Emsley; et al


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